C-C and C-N coupling reactions of an imidotitanium complex with isocyanides
Version 2 2024-03-12, 12:27
Version 1 2023-10-18, 08:17
journal contribution
posted on 2024-03-12, 12:27 authored by A. Bashall, P. E. Collier, L. H. Gade, M. McPartlin, P. Mountford, S. M. Pugh, S. Radojevic, M. Schubart, Ian Scowen, D. J. M. Trosch<p>Reaction of the imidotitanium complex (k3-N2Npy)Ti(=NtBu)(py) (1) N2Npy = (2-C5H4N)C(Me)(CH2NSiMe3) 2 with 2,6-xylylisocyanide led to double insertion of the isocyanide into the imidotitanium bond and yielded the four-membered titanacycle (k3-N2Npy)Ti-{N(tBu)C(=N-2,6-Me2C 6H3)C(=N-2,6-C6H3Me2)} (2), which was characterized by X-ray crystallography. © 2000 American Chemical Society.</p>
History
School affiliated with
- School of Chemistry (Research Outputs)
