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Concomitant polymorphs of p-iso-propylcalix[4]arene

journal contribution
posted on 2025-05-14, 15:56 authored by V.J. Smith, C.G. Marais, K. Suwińska, J. Lipkowski, A. Szumna, C. Esterhuysen, Len BarbourLen Barbour
<p>Sublimation of p-iso-propylcalix[4]arene under reduced pressure results in the concomitant formation of two new polymorphs (forms IIP and IIIP). Both forms consist of interdigitated dimers of calixarene molecules, as does the known form IP. Despite similar inclusion behaviour to that of p-tert-butylcalix[4]arene, p-iso-propylcalix[4]arene does not appear to favour the formation of a transiently porous material. © The Royal Society of Chemistry 2015.</p>

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  • School of Natural Sciences (Research Outputs)

Publication Title

CrystEngComm

Volume

17

Issue

28

Pages/Article Number

5129-5133

ISSN

14668033

Date Accepted

2015-03-11

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