Distinctive Three-Step Hysteretic Sorption of Ethane with in Situ Crystallographic Visualization of the Pore Forms in a Soft Porous Crystal
<p>A soft porous Zn(II)-MOF (1) displays distinctive three-step hysteretic breathing behavior under ethane gas pressure at ambient temperatures. In situ single-crystal X-ray diffraction analysis was carried out at 298 K using an environmental gas cell in order to elucidate the different porous forms of the breathing framework under ethane gas. The three different phases were further characterized by pressure-gradient differential scanning calorimetry and variable pressure powder X-ray diffraction analysis. © 2017 American Chemical Society.</p>
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School affiliated with
- School of Natural Sciences (Research Outputs)
Publication Title
Journal of the American Chemical SocietyVolume
140Issue
6Pages/Article Number
2145-2150External DOI
ISSN
00027863Date Accepted
2017-09-28Will your conference paper be published in proceedings?
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Differential scanning calorimetryEthaneX ray diffraction analysisalkanechemical compoundethanemethaneMIL 53 compoundunclassified drugzinc ion[[zinc3(terephthalate)2(1,2,3 triazolate)2](n,n' dimethyformamide)]n' 1n,n' dimethyformamideEthane gasGas cellPorous crystalsPowder X ray diffractionSingle crystal X-ray diffraction analysisArticlechemical reactionchemical structurecrystalcrystal structurecrystallographydifferential scanning calorimetryenvironmental temperaturegasgravimetryhysteretic sorptionin situ crystallographic visualizationisothermphase transitionporositypressure gradientsoft porous crystalsolvent effectstructure analysisX ray diffractionSingle crystals
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