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Gibbs' Paradox according to Gibbs and slightly beyond

journal contribution
posted on 2023-10-29, 12:49 authored by Fabien PaillussonFabien Paillusson
<p>The so-called Gibbs paradox is a paradigmatic narrative illustrating the necessity to account forthe N! ways of permuting N identical particles when summing over microstates. Yet, there existsome mixing scenarios for which the expected thermodynamic outcome depends on the viewpointone chooses to justify this combinatorial term. After a brief summary on Gibbs' paradox and what isthe standard rationale used to justify its resolution, we will allow ourself to question from a historicalstandpoint whether the Gibbs paradox has actually anything to do with Gibbs' work. In so doing,we also aim at shedding a new light with regards to some of the theoretical claims surrounding itsresolution. We will then turn to the statistical thermodynamics of discrete and continuous mixturesand introduce the notion of composition entropy to characterise these systems. This will enable us toaddress, in a certain sense, a curiosity pointed out by Gibbs in a paper published in 1876. Finally,we will ?nish by proposing a connexion between the results we propose and a recent extension ofthe Landauer bound regarding the minimum amount of heat to be dissipated to reset one bit ofmemory.</p>

History

School affiliated with

  • School of Mathematics and Physics (Research Outputs)

Publication Title

Molecular Physics

Volume

116

Issue

21-22

Pages/Article Number

3196-3213

Publisher

Taylor & Francis

ISSN

0026-8976

eISSN

1362-3028

Date Submitted

2018-04-13

Date Accepted

2018-03-29

Date of First Publication

2018-04-19

Date of Final Publication

2018-04-19

Date Document First Uploaded

2018-04-13

ePrints ID

31670

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